For those who doesn't want their root password on Kali Linux live USB persistent login to be reset to the default 'toor',
Step 1: Easy
Once you have changed your password using passwd root command, edit /lib/live/config/0031-root-password and comment out the line
before: usermod -p 'X014elvznJq7E' root
after: # usermod -p 'X014elvznJq7E' root
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